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    Water driven formation of channels: unusual solidstate structural transformation of a heterometallic polymer.

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    Dalton Trans_2018_47_3588–3595 .pdf (2.189Mb)
    Identifiers
    URI: http://hdl.handle.net/10835/7243
    DOI: 10.1039/c7dt04515h
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    Author/s
    Scalambra, Franco; Serrano-Ruiz, Manuel; Romerosa, Antonio
    Date
    2018-01-29
    Abstract
    The backbone hetero-organometallic polymer trans-{[RuCp(PTA)2-μ-CN-RuCp(PTA)2-μ-CoCl3]}n·(DMSO)n (1·DMSO) has been synthesized and transformed into cis-{[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}- μ-CoCl3]}n·{[RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n·(15H2O)n (2·15H2O) by addition of water to crystallization media (PTA = 1,3,5-triaza-7-phosphaadamantane). The new polymer 2·15H2O presents a nano-channeled molecular packing with pores filled by water molecules. The crystal structures of 1·DMSO and 2·15H2O and the transformation process are herein presented and discussed.
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    • Artículos de revista Proyecto CTQ2015-67384-R [35]

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