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dc.contributor.authorScalambra, Franco
dc.contributor.authorSerrano-Ruiz, Manuel
dc.contributor.authorRomerosa, Antonio
dc.date.accessioned2019-11-12T07:41:06Z
dc.date.available2019-11-12T07:41:06Z
dc.date.issued2018-01-29
dc.identifier.urihttp://hdl.handle.net/10835/7243
dc.description.abstractThe backbone hetero-organometallic polymer trans-{[RuCp(PTA)2-μ-CN-RuCp(PTA)2-μ-CoCl3]}n·(DMSO)n (1·DMSO) has been synthesized and transformed into cis-{[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}- μ-CoCl3]}n·{[RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n·(15H2O)n (2·15H2O) by addition of water to crystallization media (PTA = 1,3,5-triaza-7-phosphaadamantane). The new polymer 2·15H2O presents a nano-channeled molecular packing with pores filled by water molecules. The crystal structures of 1·DMSO and 2·15H2O and the transformation process are herein presented and discussed.es_ES
dc.language.isoenes_ES
dc.relationinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSAes_ES
dc.sourceDalton Trans., 2018, 47, 3588–3595es_ES
dc.titleWater driven formation of channels: unusual solidstate structural transformation of a heterometallic polymer.es_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversion10.1039/c7dt04515hes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1039/c7dt04515h


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