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dc.contributor.authorScalambra, Franco
dc.contributor.authorLópez-Sánchez, Belen
dc.contributor.authorRomerosa, Antonio
dc.date.accessioned2019-11-12T07:57:21Z
dc.date.available2019-11-12T07:57:21Z
dc.date.issued2018-06-22
dc.identifier.urihttp://hdl.handle.net/10835/7247
dc.description.abstractThe catalytic activities of [RuClCp(PTA)2] (1) and [RuCp(PTA)2 (H2O-κO)]OTf (2) were assessed for the redox isomerization of the cyclic allylic alcohol 2-cyclohexenol into cyclohexanone in water and biphasic media. Complex 2 showed unprecedented good TONs for the studied conversion both in water (TON = 647) and in the biphase of cyclohexene/H2O (TON = 3420) while 1 showed a lower but also good activity (water TON = 95, biphasic TON = 100). The catalytic reaction intermediate [RuCp(PTA)2(η2-C6H9OH)] CF3SO3 (3) was synthesized and characterized using NMR.es_ES
dc.language.isoenes_ES
dc.relationinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSAes_ES
dc.sourceDalton Trans., 2018, 47, 16398–16402es_ES
dc.titleGood isomerization of 2-cyclohexenol by two Ru(II) complexes, synthesis and characterization of a reaction intermediatees_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt02560f#!divAbstractes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1039/c8dt02560f


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