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Good isomerization of 2-cyclohexenol by two Ru(II) complexes, synthesis and characterization of a reaction intermediate
dc.contributor.author | Scalambra, Franco | |
dc.contributor.author | López-Sánchez, Belen | |
dc.contributor.author | Romerosa, Antonio | |
dc.date.accessioned | 2019-11-12T07:57:21Z | |
dc.date.available | 2019-11-12T07:57:21Z | |
dc.date.issued | 2018-06-22 | |
dc.identifier.uri | http://hdl.handle.net/10835/7247 | |
dc.description.abstract | The catalytic activities of [RuClCp(PTA)2] (1) and [RuCp(PTA)2 (H2O-κO)]OTf (2) were assessed for the redox isomerization of the cyclic allylic alcohol 2-cyclohexenol into cyclohexanone in water and biphasic media. Complex 2 showed unprecedented good TONs for the studied conversion both in water (TON = 647) and in the biphase of cyclohexene/H2O (TON = 3420) while 1 showed a lower but also good activity (water TON = 95, biphasic TON = 100). The catalytic reaction intermediate [RuCp(PTA)2(η2-C6H9OH)] CF3SO3 (3) was synthesized and characterized using NMR. | es_ES |
dc.language.iso | en | es_ES |
dc.relation | info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSA | es_ES |
dc.source | Dalton Trans., 2018, 47, 16398–16402 | es_ES |
dc.title | Good isomerization of 2-cyclohexenol by two Ru(II) complexes, synthesis and characterization of a reaction intermediate | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt02560f#!divAbstract | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1039/c8dt02560f |