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    Molecular Insights into Bulk and Porous κ2P,N-PTA Metal- Organic Polymers by Simultaneous Raman Spectroscopy and Inelastic Neutron Scattering.

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    Paper accepted but not corrected. (1.334Mb)
    Identifiers
    URI: http://hdl.handle.net/10835/7248
    DOI: 10.1002/ejic.201801283
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    Author/s
    Scalambra, Franco; Rudic, Svemir; Romerosa, Antonio
    Date
    2018-12-17
    Abstract
    Simultaneous Raman spectroscopy and inelastic neutron scattering have been used to obtain structural information about the isomeric metal-organic polymers trans-[{RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]n·(DMSO)n (2), cis- {[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]}n·{[RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n·(15H2O)n (3) and {[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]}n·{[RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n (4) (PTA = 1,3,5-triaza- 7-phosphaadamantane). Despite the complexity of the compounds, the combination of both techniques has been useful to understand the conformation-dependent fingerprint of the polymers and, at the same time, to obtain preliminary information about how the water molecules are confined in the structural channels of 3.
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    • Artículos de revista Proyecto CTQ2015-67384-R [35]

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