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dc.contributor.authorScalambra, Franco
dc.contributor.authorRudic, Svemir
dc.contributor.authorRomerosa, Antonio
dc.date.accessioned2019-11-12T08:14:55Z
dc.date.available2019-11-12T08:14:55Z
dc.date.issued2018-12-17
dc.identifier.urihttp://hdl.handle.net/10835/7248
dc.description.abstractSimultaneous Raman spectroscopy and inelastic neutron scattering have been used to obtain structural information about the isomeric metal-organic polymers trans-[{RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]n·(DMSO)n (2), cis- {[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]}n·{[RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n·(15H2O)n (3) and {[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}-μ-CoCl3]}n·{[RuCp- (PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n (4) (PTA = 1,3,5-triaza- 7-phosphaadamantane). Despite the complexity of the compounds, the combination of both techniques has been useful to understand the conformation-dependent fingerprint of the polymers and, at the same time, to obtain preliminary information about how the water molecules are confined in the structural channels of 3.es_ES
dc.language.isoenes_ES
dc.relationinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSAes_ES
dc.sourceEur. J. Inorg. Chem. 2019, 1155–1161es_ES
dc.titleMolecular Insights into Bulk and Porous κ2P,N-PTA Metal- Organic Polymers by Simultaneous Raman Spectroscopy and Inelastic Neutron Scattering.es_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/ejic.201801283es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1002/ejic.201801283


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