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dc.contributor.authorScalambra, Franco
dc.contributor.authorHolzmann, Nicole
dc.contributor.authorBernasconi, Leonardo
dc.contributor.authorImberti, Silvia
dc.contributor.authorRomerosa, Antonio
dc.date.accessioned2019-11-12T08:16:54Z
dc.date.available2019-11-12T08:16:54Z
dc.date.issued2019-01-30
dc.identifier.urihttp://hdl.handle.net/10835/7249
dc.description.abstractThe nature of the interaction of water molecules with cis-[Ru(bpy)2(PTA)2]Cl2 (1Cl2) and trans-[Ru(bpy)2(PTA)2]F2 (2F2) in aqueous solution was studied using neutron scattering and electronic structure calculations. Both complexes were obtained in grams by a new synthetic procedure, and their response to UV/Vis radiation was examined using calculations. The new complex 2F2 was characterised by elemental analysis, NMR and IR spectroscopy. Complex 2F2 was also fully characterised by single-crystal X-ray diffraction. An analysis based on neutron diffraction data and ab initio calculations was used to study the solvent distribution around the two complexes, and to link the solvent environment to specific features in the optical response of their solutions.es_ES
dc.language.isoenes_ES
dc.relationinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSAes_ES
dc.sourceEur. J. Inorg. Chem. 2019, 1162–1169es_ES
dc.titleThe Interaction of Water with cis and trans {Ru(bpy)2(PTA)2}2+ (PTA = 1,3,5-Triaza-7-phosphaadamantane) Studied by Neutron Scattering and Ab Initio Calculationses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/ejic.201801499es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1002/ejic.201801499


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