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dc.contributor.authorScalambra, Franco
dc.contributor.authorLorenzo-Luis, Pablo
dc.contributor.authorde los Rios, Isaac
dc.contributor.authorRomerosa, Antonio
dc.date.accessioned2019-11-12T08:29:13Z
dc.date.available2019-11-12T08:29:13Z
dc.date.issued2019-04-27
dc.identifier.urihttp://hdl.handle.net/10835/7251
dc.description.abstractIsomerisation of allylic alcohols in water mediated catalytically by water soluble metal complexes is an elegant synthetic procedure for obtaining carbonyl compounds in a completely atom-economical ecobenign process with several useful applications in natural-product synthesis and in bulk chemical processes. This review is targeted to provide a general view of the goals obtained in isomerisation catalysis in water. Complexes that catalyze the isomerization of allylic alcohols in water, together with ligands and reaction conditions are compared with respect to yield, turnovers, rate and selectivity. A general overview of the mechanisms proposed for the isomerisation of allylic alcohols is also presented. Crystal structures and selected bond lengths are presented for the most representative catalytically active metal complexes.es_ES
dc.language.isoenes_ES
dc.relationinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSAes_ES
dc.titleIsomerization of allylic alcohols in water catalyzed by transition metal complexeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0010854519300657?via%3Dihubes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi/doi.org/10.1016/j.ccr.2019.04.012


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