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A Concise Route for the Synthesis of Tetracyclic Meroterpenoids: (±)-Aureol Preparation and Mechanistic Interpretation
dc.contributor.author | Rosales Martínez, Antonio | |
dc.contributor.author | Enríquez, Lourdes | |
dc.contributor.author | Jaraíz, Martín | |
dc.contributor.author | Pozo Morales, Laura | |
dc.contributor.author | Rodríguez García, Ignacio Manuel | |
dc.contributor.author | Díaz Ojeda, Emilio | |
dc.date.accessioned | 2020-09-02T10:44:34Z | |
dc.date.available | 2020-09-02T10:44:34Z | |
dc.date.issued | 2020-08-26 | |
dc.identifier.issn | 1660-3397 | |
dc.identifier.uri | http://hdl.handle.net/10835/8413 | |
dc.description.abstract | A new concise general methodology for the synthesis of different tetracyclic meroterpenoids is reported: (±)-aureol (1), the key intermediate of this general route. The synthesis of (±)-aureol (1) was achieved in seven steps (28% overall yield) from (±)-albicanol. The key steps of this route include a C–C bond-forming reaction between (±)-albicanal and a lithiated arene unit and a rearrangement involving 1,2-hydride and 1,2-methyl shifts promoted by BF3•Et2O as activator and water as initiator. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | MDPI | es_ES |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | aureol | es_ES |
dc.subject | tetracyclic meroterpenoids | es_ES |
dc.subject | natural products synthesis | es_ES |
dc.title | A Concise Route for the Synthesis of Tetracyclic Meroterpenoids: (±)-Aureol Preparation and Mechanistic Interpretation | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/1660-3397/18/9/441 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |