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First 3-D Ru-Ru-Au organometallic polymer with layered structure
dc.contributor.author | Scalambra, Franco | |
dc.contributor.author | Sierra-Martin, Benjamin | |
dc.contributor.author | Serrano-Ruiz, Manuel | |
dc.contributor.author | Fernandez-Barbero, Antonio | |
dc.contributor.author | Romerosa, Antonio | |
dc.date.accessioned | 2021-05-17T06:46:47Z | |
dc.date.available | 2021-05-17T06:46:47Z | |
dc.date.issued | 2020-07-02 | |
dc.identifier.issn | 1364-548X | |
dc.identifier.uri | http://hdl.handle.net/10835/10774 | |
dc.description.abstract | A new water soluble heterometallic polymeric complex [{(PTA)2 CpRu-l-CN-1jC:2j2N-RuCp(PTA)2}-l-{Au(CN)4}4]n 2H2O (1) is synthesized and characterized by single crystal X-ray diffraction. This complex self-assembles forming 3D polymeric structures with large scale hexagonal conformation. They also organize as 3D stacks of polymer sandwiches that can be exfoliated providing mono heterometallic-3D layers, as shown by electron microscopy. Regarding the polymer dynamics, quasi-elastic neutron scattering shows a transition from vibrational Debye–Waller behaviour to a more dynamically active state as a result of the loss of structural water molecules. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | RSC | es_ES |
dc.relation | info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSA | es_ES |
dc.subject | Chemistry | es_ES |
dc.title | First 3-D Ru-Ru-Au organometallic polymer with layered structure | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | 10.1039/d0cc04325g | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |