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Stereoselective Barbier Type Allylations and Propargylations Mediated by CpTiCl3
| dc.contributor.author | López Martínez, Josefa Leticia | |
| dc.contributor.author | Torres García, Irene | |
| dc.contributor.author | Rodríguez García, Ignacio Manuel | |
| dc.contributor.author | Muñoz Dorado, Manuel | |
| dc.contributor.author | Álvarez Corral, Míriam | |
| dc.date.accessioned | 2023-12-04T07:24:42Z | |
| dc.date.available | 2023-12-04T07:24:42Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | J. Org. Chem. 2019, 84, 2, 806–816 | es_ES |
| dc.identifier.uri | http://hdl.handle.net/10835/14713 | |
| dc.description.abstract | CpTiCl2, prepared in situ by manganese reduction of CpTiCl3, is an excellent new system for the Barbier-type allylation and propargylation of carbonyl compounds. It can be used in catalytic amounts when combined with Et3N•HBr/TMSBr, which act as regenerating system. The high regio- and stereoselectivity shown by this system makes it useful for prenylation and crotylation processes in synthesis of natural products. | es_ES |
| dc.language.iso | en | es_ES |
| dc.publisher | American Chemical Society | es_ES |
| dc.source | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [J. Org. Chem. 2019, 84, 2, 806–816], copyright © [Copyright © 2018 American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/doi/10.1021/acs.joc.8b02643] | es_ES |
| dc.subject | Organic Chemistry | es_ES |
| dc.title | Stereoselective Barbier Type Allylations and Propargylations Mediated by CpTiCl3 | es_ES |
| dc.type | info:eu-repo/semantics/article | es_ES |
| dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.joc.8b02643 | es_ES |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
| dc.identifier.doi | https://doi.org/10.1021/acs.joc.8b02643 |
