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Deconjugative α‑Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids
dc.contributor.author | Chahboun, Rachid | |
dc.contributor.author | Botubol-Ares, José Manuel | |
dc.contributor.author | Durán-Peña, María Jesús | |
dc.contributor.author | Jiménez, Fermín | |
dc.contributor.author | Alvarez-Manzaneda Roldán, Ramón Jesús | |
dc.contributor.author | Alvarez-Manzaneda, Enrique | |
dc.date.accessioned | 2024-03-07T09:50:20Z | |
dc.date.available | 2024-03-07T09:50:20Z | |
dc.date.issued | 2021-06-15 | |
dc.identifier.citation | J. Org. Chem. 2021, 86, 8742−8754 | es_ES |
dc.identifier.issn | 0022-3263 | |
dc.identifier.uri | http://hdl.handle.net/10835/16130 | |
dc.description.abstract | A general and efficient method for the deconjugative α-alkylation of α,β-unsaturated aldehydes promoted by a synergistic effect between tBuOK and NaH, which considerably increases the reaction rate under mild conditions, is reported. The β,γ-unsaturated aldehyde, resulting from the α-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids. | es_ES |
dc.language.iso | en | es_ES |
dc.title | Deconjugative α‑Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.joc.1c00560 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1021/acs.joc.1c00560 |