Lead(IV) acetate oxidative ring-opening of 2,3-epoxy primary alcohols: a new entry to optically active α-hydroxy carbonyl compounds

dc.contributor.author	Alvarez-Manzaneda, Enrique
dc.contributor.author	Chahboun, Rachid
dc.contributor.author	Alvarez, Esteban
dc.contributor.author	Alvarez-Manzaneda Roldán, Ramón Jesús
dc.contributor.author	Muñoz, Pedro E.
dc.contributor.author	Jiménez, Fermín
dc.contributor.author	Bouanou, Hanane
dc.date.accessioned	2024-04-12T09:24:32Z
dc.date.available	2024-04-12T09:24:32Z
dc.date.issued	2011-05-25
dc.identifier.citation	Tetrahedron Lett. 2011, 4017	es_ES
dc.identifier.issn	0040-4039
dc.identifier.uri	http://hdl.handle.net/10835/16285
dc.description.abstract	The treatment of 2,3-epoxy primary alcohols with lead(IV) acetate (LTA) leads to α-acetoxy aldehydes or α-acetoxy ketones, through the nucleophilic ring-opening of an intermediate oxonium and the subsequent carbon–carbon bond cleavage. This reaction represents a new route to optically active α-hydroxy carbonyl compounds.	es_ES
dc.language.iso	en	es_ES
dc.publisher	Elsevier	es_ES
dc.subject	Hydroxycarbonyl compounds	es_ES
dc.subject	Allyl alcohols	es_ES
dc.subject	Asymmetric synthesis	es_ES
dc.subject	Lead tetraacetate	es_ES
dc.title	Lead(IV) acetate oxidative ring-opening of 2,3-epoxy primary alcohols: a new entry to optically active α-hydroxy carbonyl compounds	es_ES
dc.type	info:eu-repo/semantics/article	es_ES
dc.relation.publisherversion	https://www.sciencedirect.com/science/article/pii/S0040403911008859?via%3Dihub	es_ES
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es_ES
dc.identifier.doi	10.1016/j.tetlet.2011.05.116