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Oxidative Coupling of (−)-Sclareol and Related Diols Leading to Oxepane Terpenoids
dc.contributor.author | Bouanou, Hanane | |
dc.contributor.author | Gil, Juan A. | |
dc.contributor.author | Alvarez-Manzaneda Roldán, Ramón Jesús | |
dc.contributor.author | Chahboun, Rachid | |
dc.contributor.author | Alvarez-Manzaneda, Enrique | |
dc.date.accessioned | 2024-04-12T13:22:55Z | |
dc.date.available | 2024-04-12T13:22:55Z | |
dc.date.issued | 2016-09-30 | |
dc.identifier.citation | J. Org. Chem. 2016, 81, 10002−10008 | es_ES |
dc.identifier.issn | 0022-3263 | |
dc.identifier.uri | http://hdl.handle.net/10835/16344 | |
dc.description.abstract | Treatment of (−)-sclareol and related compounds with lead tetraacetate affords tetracyclic compounds bearing a 2,8- dioxabicyclo[5.2.0]nonane moiety with complete regio- and stereoselectivity. This process, which is also applicable to 1,5-diols with a similar substitution pattern, facilitates the development of efficient syntheses toward oxepane terpenoids, such as aplysistatin derivatives. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.title | Oxidative Coupling of (−)-Sclareol and Related Diols Leading to Oxepane Terpenoids | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acs.joc.6b01834 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1021/acs.joc.6b01834 |