Synthesis of the Putative Structure of 15-Oxopuupehenoic Acid

dc.contributor.author	Boulifa, Ettahir
dc.contributor.author	Fernández, Antonio
dc.contributor.author	Alvarez, Esteban
dc.contributor.author	Alvarez-Manzaneda Roldán, Ramón Jesús
dc.contributor.author	Ibn Mansour, Ahmed
dc.contributor.author	Chahboun, Rachid
dc.contributor.author	Alvarez-Manzaneda, Enrique
dc.date.accessioned	2024-04-12T13:23:48Z
dc.date.available	2024-04-12T13:23:48Z
dc.date.issued	2014-10-02
dc.identifier.citation	J. Org. Chem. 2014, 79, 10689−10695	es_ES
dc.identifier.issn	0022-3263
dc.identifier.uri	http://hdl.handle.net/10835/16345
dc.description.abstract	Synthesis of the putative structure of the marine natural 15-oxopuupehenoic acid has been achieved starting from commercial (−)-sclareol. Key steps of the synthetic sequence are the Robinson annulation of a β-ketoester and methyl vinyl ketone and an unprecedented cyclization of the resulting α,β-enone, which is mediated by tin(IV) chloride in the presence of N-phenylselenophthalimide. The physical properties of the synthetic compound are somewhat different from those reported for the natural product.	es_ES
dc.language.iso	en	es_ES
dc.title	Synthesis of the Putative Structure of 15-Oxopuupehenoic Acid	es_ES
dc.type	info:eu-repo/semantics/article	es_ES
dc.relation.publisherversion	https://pubs.acs.org/doi/10.1021/jo502048y	es_ES
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es_ES
dc.identifier.doi	10.1021/jo502048y