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First enantiospecific synthesis of marine sesquiterpene quinol akaol A
dc.contributor.author | Alvarez-Manzaneda, Enrique | |
dc.contributor.author | Chahboun, Rachid | |
dc.contributor.author | Alvarez, Esteban | |
dc.contributor.author | Fernández, Antonio | |
dc.contributor.author | Alvarez-Manzaneda Roldán, Ramón Jesús | |
dc.contributor.author | Haidöur, Ali | |
dc.contributor.author | Ramos, Jose M. | |
dc.contributor.author | Akhaouzan, Ali | |
dc.date.accessioned | 2024-04-12T13:27:01Z | |
dc.date.available | 2024-04-12T13:27:01Z | |
dc.date.issued | 2011-10-27 | |
dc.identifier.citation | Chem. Commun., 2012, 48, 606–608 | es_ES |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | http://hdl.handle.net/10835/16348 | |
dc.description.abstract | The first enantiospecific synthesis of akaol A, a marine sesquiterpene quinol, has been achieved. Key steps of the synthetic sequence are the oxidative degradation of (-)-sclareol to a dinorlabdane ketoester, mediated by the ozone–lead(IV) acetate system, the diastereoselective α-methylation of a ketoaldehyde, followed by an intramolecular aldol condensation and the further Diels–Alder cycloaddition of a dienol ether. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.title | First enantiospecific synthesis of marine sesquiterpene quinol akaol A | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2012/cc/c1cc14608d | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1039/c1cc14608d |