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Lead(IV) acetate mediated cleavage of β-hydroxy ethers: enantioselective synthesis of α-acetoxy carbonyl compounds

dc.contributor.authorAlvarez-Manzaneda, Enrique
dc.contributor.authorChahboun, Rachid
dc.contributor.authorAlvarez, Esteban
dc.contributor.authorAlvarez-Manzaneda Roldán, Ramón Jesús 
dc.contributor.authorMuñoz, Pedro E.
dc.contributor.authorJiménez, Pedro E.
dc.contributor.authorBouanou, Hanane
dc.date.accessioned2024-04-12T13:27:18Z
dc.date.available2024-04-12T13:27:18Z
dc.date.issued2011-09-14
dc.identifier.citationTetrahedron 2011, 8910es_ES
dc.identifier.issn0040-4020
dc.identifier.urihttp://hdl.handle.net/10835/16349
dc.description.abstractα-Acetoxy aldehydes or α-acetoxy ketones can be efficiently synthesized by treating 2,3-epoxy primary alcohols with lead tetraacetate. The reaction, which proceeds with complete regio- and stereoselectivity facilitates the enantioselective synthesis of α-acetoxy carbonyl compounds from allyl alcohols, via Sharpless epoxidation. Cyclic β-hydroxy ethers, with an oxygenated five-, six- or seven-membered ring, are transformed into α-acetoxy ethers.es_ES
dc.language.isoenes_ES
dc.publisherElsevieres_ES
dc.subjectHydroxycarbonyl compoundses_ES
dc.subjectAllyl alcoholses_ES
dc.subjectAsymmetric synthesises_ES
dc.subjectLead tetraacetatees_ES
dc.subjectHydroxy etherses_ES
dc.titleLead(IV) acetate mediated cleavage of β-hydroxy ethers: enantioselective synthesis of α-acetoxy carbonyl compoundses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S004040201101413X?via%3Dihubes_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1016/j.tet.2011.09.056


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