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A short route towards merosesquiterpenes with a benzoxanthene skeleton
dc.contributor.author | Fernández, Antonio | |
dc.contributor.author | Alvarez, Esteban | |
dc.contributor.author | Alvarez-Manzaneda Roldán, Ramón Jesús | |
dc.contributor.author | Chahboun, Rachid | |
dc.contributor.author | Alvarez-Manzaneda, Enrique | |
dc.date.accessioned | 2024-04-12T13:30:21Z | |
dc.date.available | 2024-04-12T13:30:21Z | |
dc.date.issued | 2014-09-03 | |
dc.identifier.citation | Chem. Commun., 2014, 50, 13100 | es_ES |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | http://hdl.handle.net/10835/16355 | |
dc.description.abstract | A short synthetic sequence for the preparation of merosesquiterpenes with a benzoxanthene skeleton starting from commercial (-)-sclareol is reported. The D ring of the target compound is obtained through a Diels–Alder cycloaddition, involving a dienoldiether derived from a tricyclic α,β-enone synthesized in two steps from the starting diterpene. Utilizing this procedure, the preparation of (+)-hongoquercin A and the first synthesis of (+)-cyclospongiaquinone-1 were achieved. | es_ES |
dc.language.iso | en | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.title | A short route towards merosesquiterpenes with a benzoxanthene skeleton | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc05116e | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.identifier.doi | 10.1039/c4cc05116e |