TY - GEN AU - Scalambra, Franco AU - López-Sánchez, Belen AU - Holzmann, Nicole AU - Bernasconi, Leonardo AU - Romerosa Nievas, Antonio Manuel PY - 2020 UR - http://hdl.handle.net/10835/15049 AB - The isomerization of 1-penten-3-ol into 3-pentanone catalyzed by [RuCp(H2O-κO)(PTA)2](CF3SO3) (1CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) was studied and two watersoluble ruthenium catalyst reaction intermediates were characterized. The... LA - en KW - Alcohols KW - Crystal structure KW - Isomerization KW - Ligands KW - Molecular structure TI - Steps ahead in understanding the catalytic isomerization mechanism of linear allylic alcohols in water: dynamics, bonding analysis and crystal structure of a 2-allyl-intermediate. ER -