TY - GEN AU - Alvarez-Manzaneda, Enrique AU - Chahboun, Rachid AU - Alvarez, Esteban AU - Alvarez-Manzaneda Roldán, Ramón Jesús AU - Muñoz, Pedro E. AU - Jiménez, Fermín AU - Bouanou, Hanane PY - 2011 SN - 0040-4039 UR - http://hdl.handle.net/10835/16285 AB - The treatment of 2,3-epoxy primary alcohols with lead(IV) acetate (LTA) leads to α-acetoxy aldehydes or α-acetoxy ketones, through the nucleophilic ring-opening of an intermediate oxonium and the subsequent carbon–carbon bond cleavage. This reaction... LA - en PB - Elsevier KW - Hydroxycarbonyl compounds KW - Allyl alcohols KW - Asymmetric synthesis KW - Lead tetraacetate TI - Lead(IV) acetate oxidative ring-opening of 2,3-epoxy primary alcohols: a new entry to optically active α-hydroxy carbonyl compounds DO - 10.1016/j.tetlet.2011.05.116 ER -