Water driven formation of channels: unusual solidstate structural transformation of a heterometallic polymer.

dc.contributor.author	Scalambra, Franco
dc.contributor.author	Serrano-Ruiz, Manuel
dc.contributor.author	Romerosa, Antonio
dc.date.accessioned	2019-11-12T07:41:06Z
dc.date.available	2019-11-12T07:41:06Z
dc.date.issued	2018-01-29
dc.identifier.uri	http://hdl.handle.net/10835/7243
dc.description.abstract	The backbone hetero-organometallic polymer trans-{[RuCp(PTA)2-μ-CN-RuCp(PTA)2-μ-CoCl3]}n·(DMSO)n (1·DMSO) has been synthesized and transformed into cis-{[{RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2}- μ-CoCl3]}n·{[RuCp(PTA)2-μ-CN-1κC:2κ2N-RuCp(PTA)2]Cl}0.5n·(15H2O)n (2·15H2O) by addition of water to crystallization media (PTA = 1,3,5-triaza-7-phosphaadamantane). The new polymer 2·15H2O presents a nano-channeled molecular packing with pores filled by water molecules. The crystal structures of 1·DMSO and 2·15H2O and the transformation process are herein presented and discussed.	es_ES
dc.language.iso	en	es_ES
dc.relation	info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67384-R/ES/Polímeros poliheteroorganmetálicos fluorecentes solubles en agua/PPFSA	es_ES
dc.source	Dalton Trans., 2018, 47, 3588–3595	es_ES
dc.title	Water driven formation of channels: unusual solidstate structural transformation of a heterometallic polymer.	es_ES
dc.type	info:eu-repo/semantics/article	es_ES
dc.relation.publisherversion	10.1039/c7dt04515h	es_ES
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es_ES
dc.identifier.doi	10.1039/c7dt04515h